one-pot reaction of aldehydes or ketons with aniline derivatives was performed using nabh4 and fe3o4 magnetic nanoparticles (mnps). the optimum amount of fe3o4 mnps was 5 mol% under solvent free condition. the corresponding products were obtained in good to excellent yields. the magnetically recoverable iron oxide nanoparticles are found to be efficient for synthesis of amine derivatives. these...

acylisothiocyanate (1) was allowed to react with benzylidene malononitrile producing oxazine derivative (2). also, compound (1) was reacted with sodium azide followed by refluxing with sodium ethoxide affording thiazinotetrazole derivative (4). the reaction of acetylacetone with compound (1) gave pyridine derivative (5) by intramolecular cycloaddition while it was reacted with n-methyl aniline ...

Acylisothiocyanate (1) was allowed to react with benzylidene malononitrile producing oxazine derivative (2). Also, compound (1) was reacted with sodium azide followed by refluxing with sodium ethoxide affording thiazinotetrazole derivative (4). The reaction of acetylacetone with compound (1) gave pyridine derivative (5) by intramolecular cycloaddition while it was reacted with N-methyl aniline ...

The effect of three aromatic amines namely aniline (AN), dimethyl aniline (DMAN) and diethyl aniline (DEAN) on emission properties of a coumarin derivative 6-methyl-3azidoacetyl coumarin (6M3AAC) in acetonitrile was studied by means of steady state fluorescence spectroscopy. The quenching of fluorescence intensity was observed in the presence of amines. The quenching process was characterized b...

The effect of three aromatic amines namely aniline (AN), dimethyl aniline (DMAN) and diethyl aniline (DEAN) on emission properties of a coumarin derivative 6-methyl-3azidoacetyl coumarin (6M3AAC) in acetonitrile was studied by means of steady state fluorescence spectroscopy. The quenching of fluorescence intensity was observed in the presence of amines. The quenching process was characterized b...

The carcinogen aniline is negative in the Ames Salmonella mutagenicity assay. Aniline does, however, induce intrachromosomal recombination between repeated sequences in Saccharomyces cerevisiae, resulting in deletion (DEL) of intervening sequences. We have investigated whether the generation of oxidative free radical species by aniline and/ or its metabolites may be responsible for its recombin...

A three-step procedure for the synthesis of multifunctionalized heterocycles from a pyroglutamic acid derivative, glycidyl components and anilines by nucleophilic substitution and cobalt catalysis is presented.

The reaction of 2-(2-phenylethynyl)aniline with acetone in presence of [IrCp*Cl(2)](2) has previously been found to yield a vinyl indole derivative and not the indole expected to form following a hydroamination reaction. Experimental data, including labelling studies, isolation and solid state structure determination of a reaction intermediate together with DFT calculations were used to develop...

The synthesis and photophysical properties of the dihydroxypropylamide derivative of pyrene-1,6-dicaboxamide, its aniline dyad, and DNA conjugates are reported. The dicarboxamide serves as a hairpin linker for bis(oligonucleotide) conjugates having short base pair stems. The dihydroxypropyl derivative has a large fluorescence quantum yield and long singlet decay time, as determined by fluoresce...